Elastic continuum theory cutoffs and order in nematics and solids
- 1 February 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (3) , 776-778
- https://doi.org/10.1063/1.430525
Abstract
Thermal disorder in liquid crystal molecular orientation and thermal displacement of atoms in monatomic crystals can be described with analogous elastic continuum theories having short wavelength cutoffs. Half the short wavelength cutoff that gives the observed displacement is remarkably close to 1.8 times the cube root of the atomic volume in monatomic crystals. Half the short wavelength cutoff that gives the observed order parameter in PAA is also about 1.8 times the cube root of the molecular volume. Some data give a number about twice as large for MBBA. This large cutoff may be due to a large error in measured order parameter, or it may suggest that MBBA molecules tend to form groups in the nematic phase.Keywords
This publication has 5 references indexed in Scilit:
- Nuclear Spin-Lattice Relaxation in Liquid Crystals by Fluctuations in the Nematic DirectorPhysical Review Letters, 1974
- Elastic Constants of the Nematic Liquid Crystalline Phase of p-Methoxybenzylidene-p-n-Butylaniline (MBBA)The Journal of Chemical Physics, 1972
- Temperature Dependence of Orientational Order in a Nematic Liquid Crystal at Constant Molar VolumePhysical Review Letters, 1972
- Quasielastic Rayleigh Scattering in Nematic Liquid CrystalsPhysical Review Letters, 1969
- I. Liquid crystals. On the theory of liquid crystalsDiscussions of the Faraday Society, 1958