STUDIES IN THE PYRROLINE SERIES: V. 3,3-DIMETHYL-1-PYRROLINE-1-OXIDE
- 1 October 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (10) , 2717-2723
- https://doi.org/10.1139/v65-381
Abstract
The pyrolysis of 1-ethyl-3,3-dimethylpyrrolidine-1-oxide gives 1-hydroxy-3,3-dimethylpyrrolidine, which, on dehydrogenation, yields 3,3-dimethyl-1-pyrroline-1-oxide. The identification of the nitrone is described. The cyclo-additions of styrene to this nitrone and to 5,5-dimethyl-1-pyrroline-1-oxide were investigated, and the direction of addition was deduced from the n.m.r. spectra of the adducts.Keywords
This publication has 8 references indexed in Scilit:
- STUDIES IN THE PYRROLINE SERIES: I. THE PROTON MAGNETIC RESONANCE SPECTRA OF SOME PYRROLINESCanadian Journal of Chemistry, 1962
- STUDIES IN THE PYRROLINE SERIES: II. OXYGEN TRANSFER FROM CYCLIC NITRONES TO TRIPHENYLPHOSPHINECanadian Journal of Chemistry, 1962
- THE CONFIGURATION AND CONFORMATION OF THYMIDINECanadian Journal of Chemistry, 1961
- 1.3-Dipolare additionen der nitroneTetrahedron Letters, 1960
- THE ADDITION OF NITRONES TO OLEFINS. A NEW ROUTE TO ISOXAZOLIDINESJournal of the American Chemical Society, 1959
- Azo Compounds.1 Oxidation of 1,1-Disubstituted Hydrazines. The Synthesis and Oxidation of cis- and trans-1-Amino-2,6-diphenylpiperidine. A New Stereospecific Ring ClosureJournal of the American Chemical Society, 1957
- The Preparation of Geminally Substituted 4-Bromobutylamines. II. 4-Bromo-2,2-dialkyl- and diarylbutylamines1Journal of the American Chemical Society, 1955
- Addition Reactions of Nitroalkanes with Acrolein and Methyl Vinyl Ketone. Selective Reduction of Nitrocarbonyl Compounds to NitrocarbinolsJournal of the American Chemical Society, 1952