Nafion-H Catalyzed Isomerization of Glycidic to α-Hydroxy-β,γ-unsaturated Esters: Application in the Synthesis of a Trifluoromethylated Vinylic Epoxide

Abstract
Facile Nafion-H catalyzed isomerization of glycidic esters to α-hydroxy-β,γ-unsaturated esters is reported. These compounds are useful synthetic intermediates. Application in the synthesis of a trifluoromethylated vinylic epoxide is demonstrated.

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