Stable cationic monoalkylcarbonate complexes of ruthenium(II) from the reactions of CO2 with alcohol solutions of ruthenium hydrides
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 204-205
- https://doi.org/10.1039/c39760000204
Abstract
The salt [Ru(O2COR)(PMe2Ph)4]PF6,(R = Me,Et), containing a bidentate monoalkylcarbonate ester, is produced from the reaction of [RuH(PMe2Ph)5]PF6 and CO2 in methanol or ethanol or by recrystallising the format complex [Ru(O2CH)(PMe2Ph)4]PF6 from acetone-ROH(R = Me, Et).Keywords
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