Activation energies for the elimination of hydrogen fluoride from alkyl fluorides obtained by the activated molecule and competitive shock-tube techniques
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 4,p. 203-204
- https://doi.org/10.1039/c29700000203
Abstract
Critical energies for the elimination of hydrogen fluoride from a series of alkyl fluorides have been determined by the activated molecule technique by application of RRKM treatment and confirmed by determination of Arrhenius parameters in competitive shock-tube experiments; the reactivities of alkyl fluorides fit the pattern established for chlorides, bromides, and iodides.Keywords
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