Equilibria in Free-Radical Chemistry: An Ab Initio Study of Hydrogen Atom Transfer Reactions between Silyl, Germyl, and Stannyl Radicals and Their Hydrides
- 20 February 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 17 (6) , 1079-1084
- https://doi.org/10.1021/om9709906
Abstract
No abstract availableKeywords
This publication has 14 references indexed in Scilit:
- On the radical Brook and related reactions: an ab initio study of some (1,2)-silyl, germyl and stannyl translocationsJournal of the Chemical Society, Perkin Transactions 2, 1997
- Stannanes as free-radical reducing agents: an ab initio study of hydrogen atom transfer from some trialkyltin hydrides to alkyl radicalsJournal of the Chemical Society, Perkin Transactions 2, 1997
- Energies of Activation. The Paradigm of Hydrogen Abstractions by RadicalsJournal of the American Chemical Society, 1995
- On the existence of SH3, SeH3, and TeH3: Discrepancies between all‐electron and pseudopotential calculationsJournal of Computational Chemistry, 1995
- Photoinduced Free Radical Chemistry of the Acyl Tellurides: Generation, Inter- and Intramolecular Trapping, and ESR Spectroscopic Identification of Acyl RadicalsJournal of the American Chemical Society, 1994
- Organosilanes as radical-based reducing agents in synthesisAccounts of Chemical Research, 1992
- Tris(trimethylsilyl)silane. A new reducing agentThe Journal of Organic Chemistry, 1988
- Tri-n-butyltin Hydride as Reagent in Organic SynthesisSynthesis, 1987
- Absolute rate constants for reaction of phenyl, 2,2-dimethylvinyl, cyclopropyl, and neopentyl radicals with tri-n-butylstannane. Comparison of the radical trapping abilities of tri-n-butylstannane and -germaneJournal of the American Chemical Society, 1985
- Pyrolysis of monosilaneJournal of the American Chemical Society, 1970