Oxidatively induced carbonyl insertion and nucleophilic cleavage reactions of alkylmetal carbonyl compounds
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 163a
- https://doi.org/10.1039/c3973000163a
Abstract
Oxidation of several alkylmetal carbonyl compounds by cerium(IV) ion in methanol takes place extremely rapidly to give the methyl ester of the next higher homologous carboxylic acid, in some cases in quantitative yield.Keywords
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