Alkylaluminum Chloride Catalyzed Ene Reactions of Formaldehyde with Unsaturated Carboxylic Acids, Esters and Alcohols
- 1 January 1992
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1992 (05) , 463-465
- https://doi.org/10.1055/s-1992-26137
Abstract
Dimethylaluminum chloride and ethylaluminum sesquichloride catalyze the ene reactions of formaldehyde with the C,C-double bond of unsaturated carboxylic acids, for example oleic acid and 10-undecenoic acid, and of the respective alcohols. Ethylaluminum dichloride catalyzes the ene reactions of formaldehyde with the respective carboxylic acid esters.Keywords
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