Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation
- 31 May 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 7,p. 1246-1250
- https://doi.org/10.1039/b204190c
Abstract
The inclusion compounds of binaphthol with three isomers of xylidine have been studied in terms of their structures and infra-red spectra. Competition experiments show that the selectivity of enclathration follows the trend: 2,6-xylidine > 2,3-xylidine ≈ 3,5-xylidine. The kinetics of desolvation have been analysed and the activation energies established.Keywords
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