The Raman spectrum of [(C5H5)Fe(CO)]4: a Resonance Effect
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1160b-1161
- https://doi.org/10.1039/c2970001160b
Abstract
The deep-green colour of [(C5H5)Fe(CO)]4 suppresses Raman scattering with available light sources, but an intense polarized band has been observed at 214 cm–1, and is attributed to the symmetric Fe–Fe stretching mode, enhanced by a resonance Raman effect: the Fe–Fe force constant is estimated at 1·3 mdyn/Å.Keywords
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