A New Highly Chemo- and Regioselective Alkoxycarbonylation of Amino Alcohols and polyols
- 1 January 1990
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1990 (01) , 27-32
- https://doi.org/10.1055/s-1990-26777
Abstract
The alkoxycarbonylating carbamates 1 and 2 are readily prepared and reacted under mild conditions with polyfunctional substrates, e.g. amino acids, unsymmetrical diols, and unprotected carbohydrates (D-glucosamine and methyl α-D-glucoside), thus affording carbamates or monocarbonates in good yields and with high chemo- and regioselectivity.Keywords
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