Intramolecular addition in hex-5-enyl, hept-6-enyl, and oct-7-enyl radicals
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 472-473
- https://doi.org/10.1039/c39740000472
Abstract
Each of the radicals, hex-5-enyl, hept-6-enyl, and oct-7-enyl, undergoes intramolecular addition preferentially in that direction which affords the cyclo-alkylcarbinyl radical, because both enthalpy and entropy factors are more favourable; an approximate rate constant for 1,5-hydrogen atom transfer in hept-6-enyl radical has been determined.This publication has 0 references indexed in Scilit: