Conversion of secologanin into elenolic acid and 18-oxayohimban alkaloids

Abstract
Elenolic acid (2c) has been obtained from secologanin (1a) in accord with its proposed derivation by rearrangement of an aglycone, and converted into ajmalicine (8c), 19-epi-ajmalicine (8a), and tetrahydroalstonine (8b).

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