The reactivity of o-acylglycosyl halides. Part XI. Exchange and hydrolysis reactions of o-benzoylglycosyl bromides
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 12,p. 1466-1468
- https://doi.org/10.1039/p29740001466
Abstract
Bromide exchange reactions and the hydrolyses of a series of benzoylglycosyl bromides in acetone have been investigated. The exchange reactions are second order and occur with inversion of configuration. Only the benzoylmannosyl bromide hydrolyses at a measurable rate, but addition of lithium bromide catalyses the hydrolysis of 1,2-cis-benzoylglycosyl bromides.Keywords
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