A new class of single-molecule magnet: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S = 17/2 ground state
- 9 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 2252-2253
- https://doi.org/10.1039/b206386g
Abstract
The reaction of [Mn3O(OAc)6(py)3] with 1,1,1-tris(hydroxymethyl)ethane (H3thme) gives the Mn(IV)3Mn(III)4Mn(II)2 complex [Mn9O7(OAc)11(thme)(py)3(H2O)2], which has an S = 17/2 ground state and displays strong out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.Keywords
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