Preparation of [Fe(C5H5)(dppe)(NCCH3)]Br and Its Conversion to Several Fe(C5H5)(dppe)X Compounds
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 9 (1) , 21-29
- https://doi.org/10.1080/00945717908057448
Abstract
The compound [Fe(C5H5)(dppe)(NCCH3)]Br is conveniently prepared by irradiation of Fe(C5H5)(CO)2Br and dppe (dppe = 1,2-bis(diphenyl-phosphino)ethane) in acetonitrile. The acetonitrile ligand is easily displaced by anionic ligands (X− = CN−, SCN−, SPh−, I−, Br−, CH3 − (as CH3MgI) and H− (as LiAlH4)) to give the complexes Fe(C5H5)(dppe)X.Keywords
This publication has 13 references indexed in Scilit:
- Preparation et proprietes chimiques de l′inorganomagnesien Cp(DPPE)FeMgBrJournal of Organometallic Chemistry, 1978
- Crystal structure at -35.degree.C of (.pi.-cyclopentadienyl)(bis(diphenylphosphine)ethane)(acetonitrile)iron tetraphenylborate and evidence for cationic iron-methylene complexesInorganic Chemistry, 1978
- Reaktionen an komplexgebundenen liganden : XXI. Eisen-komplexe mit distickstoff- und stickstoffwasserstoff-liganden; synthese und eigenschaften von [C5H5Fe(dppe)L]X (L = N2, N2H4, NH3, CO, aceton, THF, H−, Cl−; X = Cl−, PF6−)Journal of Organometallic Chemistry, 1977
- Reactions of electron-rich organometallic complexesJournal of Organometallic Chemistry, 1975
- Preparation and Mössbauer spectra of some cyclopentadienyl iron complexes containing a chelating diphosphine ligandJ. Chem. Soc., Dalton Trans., 1973
- Reactions of metal carbonyl derivatives. VIII. Oxidation reactions of some ditertiary phosphine derivatives of bis(dicarbonyl-.pi.-cyclopentadienyliron)Inorganic Chemistry, 1972
- Studies on bis(triphenyl phosphite)-π-cyclopentadienyliron derivatives and related complexesJ. Chem. Soc. A, 1971
- Organometallic transition metal derivatives containing fluorine IV. Reactions of perfluoroalkyl derivatives of cyclopentadienylmetal carbonyls of iron and molybdenum with tertiary phosphinesJournal of Organometallic Chemistry, 1969
- Complexes of trivalent phosphorus derivatives. IX. Reactions of cyclopentadienylmetal carbonyl halides with chelating oligotertiary phosphinesInorganic Chemistry, 1969
- Complexes of trivalent phosphorus derivatives. V. Photochemical reactions of silicon and tin derivatives of cyclopentadienyliron dicarbonyl with trivalent phosphorus ligandsInorganic Chemistry, 1968