Molybdenum(VI) and molybdenum(V) nitrido-complexes and a µ-nitrido-molybdenumrhenium complex

1 January 1974

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 13,p. 517-518
https://doi.org/10.1039/c39740000517

Abstract

Trimethylsilyl azide is a convenient reagent for the preparation of molybdenum(VI) and molybdenum(V) nitrido-complexes, most of which are air-stable crystalline solids; the 7-co-ordinate complexes, [MoN(S₂CNR₂)₃](R = alkyl), are obtained from [MoCl₄(thf)₂], the silyl azide, and Me₃SiS₂CNR₂, or from [MoCl(S₂CNR₂)₃] and azides.

Keywords

NITRIDO
ME3SIS2CNR2
MON
CONVENIENT
ORDINATE
MOLYBDENUMRHENIUM
CRYSTALLINE
TRIMETHYLSILYL
MOCL