Bimorphic lattice theory of electrolyte solutions. Analysis of conductivity data
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 79 (11) , 1607-1611
- https://doi.org/10.1039/f29837901607
Abstract
The lattice-model adaptation of the Debye–Hückel–Onsager equivalent-conductivity equation is accomplished by substitution of 1.7476(2000NC)1/3 for the mean reciprocal radius of the ionic atmoshere. The form of higher-order terms in the conductivity equation is determined partly by data-fitting requirements and partly by theoretical analysis of the field dielectric gradient retardation effect. By curve fitting techniques the lattice theory is found to be consistent with conductivity data.Keywords
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