Tris- and tetra-perhalogenoaryl metallates of cobalt(II), nickel(II), palladium(II), and platinum(II)
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 789-790
- https://doi.org/10.1039/c39770000789
Abstract
The reaction of [Bun 4N]2[MCl4](M = Co or Ni) with LiC6F5 or LiC6Cl5, and of MCl2(tht)2(M = Pd or Pt, tht = tetrahydrothiophen) with LiC6F5 gives [Bun 4N]2[M(C6F5)4](M = Co, Ni, or Pd), [Bun 4N2]2[M(C6Cl5)4](M = Co or Ni), and [Bun 4N]2[M(C6F5)3(tht)](M = Pd or Pt) which, except for the cobalt derivatives, are stable towards heat, daylight, and atmospheric moisture.Keywords
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