AN EXPERIMENTAL STUDY OF BAND INTENSITIES IN THE FIRST POSITIVE SYSTEM OF N2: I. VIBRATIONAL TRANSITION PROBABILITIES
- 1 July 1954
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Physics
- Vol. 32 (7) , 468-474
- https://doi.org/10.1139/p54-048
Abstract
Integrated intensities of 52 bands of the N2 first positive system have been measured using a recording infrared spectrometer. These data have been interpreted as vibrational transition probabilities which were compared with theoretical values calculated under the assumption that the electronic transition moment is independent of internuclear separation. The comparison shows that the assumption is not valid for this electronic transition.Keywords
This publication has 3 references indexed in Scilit:
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- Tables of Planck’s Radiation and Photon Functions*Journal of the Optical Society of America, 1940
- The Infra-Red Radiation of NitrogenPhysical Review B, 1927