3-Center-4-Electron Bonding in [(silox)2MoNtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate
- 18 May 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (23) , 8262-8263
- https://doi.org/10.1021/ja051070e
Abstract
Article describing research on 3-center-4-electron bonding in [(silox)2Mo=NtBu]2(mu-Hg)Keywords
This publication has 15 references indexed in Scilit:
- Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)3WNO and R3PO (R = Me, Ph,tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-Picoline), Ta; silox =tBu3SiO)Inorganic Chemistry, 2003
- The Whole Story of the Two-Electron Bond, with the δ Bond as a ParadigmAccounts of Chemical Research, 2000
- Molybdenum Open-Shell Organometallics. Spin State Changes and Pairing Energy EffectsAccounts of Chemical Research, 1997
- Pyridine CN Bond Cleavage Mediated by (silox)3Nb (silox = tBu3SiO)Journal of the American Chemical Society, 1997
- Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and StructureChemical Reviews, 1996
- Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E = N, P, As): Structures of (silox)3Ta:EPh (E = P, As)Journal of the American Chemical Society, 1994
- A Complex with Three‐Coordinate Tungsten Atom: [(silox)2W-NtBu](silox = tBu3SiO)Angewandte Chemie International Edition in English, 1991
- Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-): physical, theoretical, and mechanistic investigationsJournal of the American Chemical Society, 1989
- Magnetic and spectroscopic properties of the .delta..delta.* states of tetrachlorotetrakis(trimethylphosphine)dimolybdenum and .beta.-[tetrachlorobis[1,2-bis(dimethylphosphino)ethane]dimolybdenum]: experimental determination of the energy of a triplet .delta..delta.* stateJournal of the American Chemical Society, 1985
- Electronic structure of copper acetate monohydrate based on a coupled chromophore modelTransactions of the Faraday Society, 1965