Heterobimetallic intermediates in alkene insertion reactions into a Pd–acetyl bond
- 15 January 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 211-212
- https://doi.org/10.1039/b007171o
Abstract
The reactivity of diphosphine-bridged heterobimetallic Fe–Pd alkyl complexes was evaluated for the insertion of CO, isonitriles, ethylene, methyl acrylate and norbornadienes and the crystal structures of the precursor alkyl complex, the iminoacyl derivative and the five-membered ring complex resulting from ethylene insertion into the palladium–acyl bond are reported.Keywords
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