PbCl2/Ga bimetal redox system-mediated carbon–carbon bond formation reactions between carbonyl compounds and ethyl trichloroacetate and iodoacetonitrile
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 189-191
- https://doi.org/10.1039/p19950000189
Abstract
In the presence of lead dichloride and a metallic gallium bimetal redox system, carbonyl compounds reacted with ethyl trichloroacetate and iodoacetonitrile to afford ethyl β-substituted α,α-dichloropropionates and β-hydroxy nitriles, respectively, in moderate to excellent yields.Keywords
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