Framework coordination chemistry; generalised entry into a new class of supramolecular compounds exemplified by the structures of [Mn₂(ebpy)₃(NO₃)₄]_n[where ebpy =N,N′-ethylenebis(2-pyridone)] and [Er₂(ebpyrr)₃(NO₃)₆]_n[where ebpyrr =N,N′-ethyienebis(2-pyrrolidone)]

1 January 1993

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 2,p. 207-209
https://doi.org/10.1039/c39930000207

Abstract

The ethylene-bridged bis(2-pyridone) ligand N,N′-ethylenebis(2-pyridone) and its bis(2-pyrrolidone) analogue react with manganese(II) nitrate and erbium(III) nitrate to form polymers containing 36-membered or 54-membered metallomacrocyclic rings, respectively; the 36-membered rings are linked to form a chain polymer and the 54-membered form contiguous two-dimensional sheets.

Keywords

This publication has 3 references indexed in Scilit:

Formation of a heterometallic (Hg–Gd) polymeric complex of 2-oxazolidone consisting of fused 16- and 48-membered macrocyclic rings; crystal structure of [Hg₂(C₃H₄NO₂)₄Gd(NO₃)₃]_n
Journal of the Chemical Society, Chemical Communications, 1991
Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐Organization
Angewandte Chemie International Edition in English, 1990
Äthinylierung
European Journal of Organic Chemistry, 1955

Framework coordination chemistry; generalised entry into a new class of supramolecular compounds exemplified by the structures of [Mn2(ebpy)3(NO3)4]n[where ebpy =N,N′-ethylenebis(2-pyridone)] and [Er2(ebpyrr)3(NO3)6]n[where ebpyrr =N,N′-ethyienebis(2-pyrrolidone)]

Abstract

Keywords

Framework coordination chemistry; generalised entry into a new class of supramolecular compounds exemplified by the structures of [Mn₂(ebpy)₃(NO₃)₄]_n[where ebpy =N,N′-ethylenebis(2-pyridone)] and [Er₂(ebpyrr)₃(NO₃)₆]_n[where ebpyrr =N,N′-ethyienebis(2-pyrrolidone)]