Direct formation of 3,3,6,6-Tetraaryl-1,2-dioxans from 1,1-Diarylethylenes and oxygen, catalysed by antimony(V) chloride
- 1 January 1978
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 31 (8) , 1737-1746
- https://doi.org/10.1071/ch9781737
Abstract
1,1-Diphenylethylene, 1,1-di-p-tolylethylene, 1,1-di-p-anisylethylene and 1,1-di(p-t-butylphenyl)-ethylene are converted in high yields (80- 90%) into the corresponding 3,3,6,6-tetraaryl-1,2-dioxans in the presence of oxygen and catalytic amounts of antimony(v) chloride in dichloromethane at -40° to -78° under irradiation from a tungsten lamp.Keywords
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