Ionization of Strong Electrolytes. IX. Proton Magnetic Resonance in the Ternary System HNO3—DNO3—H2O—D2O
- 1 May 1967
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (9) , 3450-3456
- https://doi.org/10.1063/1.1841238
Abstract
Nuclear magnetic resonance (NMR) was previously established as a reliable method for the determination of the degree of dissociation. The proton magnetic resonance shift has been measured in the full range of the ternary system HNO3—DNO3—H2O—D2O. The two nitric acids are about equally strong at 32°C, but at 0° deuteronitric acid is weaker, at 63° stronger than HNO3.Keywords
This publication has 10 references indexed in Scilit:
- Accurate NMR Temperature MeasurementsReview of Scientific Instruments, 1965
- Hydrogen Isotope Fractionation in Acidified Solutions of Protium and Deuterium OxideJournal of the American Chemical Society, 1963
- Résonance magnétique nucléaire du proton dans les associations moléculairesJournal de Chimie Physique et de Physico-Chimie Biologique, 1963
- Ionization of Strong Electrolytes. VIII. Temperature Coefficient of Dissociation of Strong Acids by Proton Magnetic ResonanceThe Journal of Chemical Physics, 1960
- Étude des propriétés thermodynamiques des systèmes. Acide nitrique – Eau et péroxyde d'azote. Acide nitriqueAnnales de la faculté des sciences de Toulouse Mathématiques, 1956
- Ionization of Strong Electrolytes. III. Proton Magnetic Resonance in Nitric, Perchloric, and Hydrochloric AcidsThe Journal of Chemical Physics, 1954
- Dissociation, Chemical Exchange, and the Proton Magnetic Resonance in Some Aqueous ElectrolytesThe Journal of Chemical Physics, 1953
- Density of Heavy WaterNature, 1949
- Raman Spectrum and Molecular Vibrations of Nitric and Deuteronitric AcidsJournal of the American Chemical Society, 1943
- On the Dissociation Constants of Acids in Light and Heavy WaterThe Journal of Chemical Physics, 1935