THE TITANIUM TETRACHLORIDE-PROMOTED REACTION OF KETENE ALKYL TRIALKYLSILYL ACETALS WITH ACETALS OR AN ORTHOFORMATE
- 5 July 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 5 (7) , 769-770
- https://doi.org/10.1246/cl.1976.769
Abstract
In the presence of TiCl4, ketene alkyl trialkylsilyl acetals reacted with acetals or an orthoformate at −78°C to afford the corresponding β-alkoxyesters or β,β-dialkoxyester in good yields, respectively.Keywords
This publication has 1 reference indexed in Scilit:
- Preparation and Physical Properties of n-Alkyl β-n-AlkoxypropionatesJournal of the American Chemical Society, 1947