Intramolecular general base catalysis by the ionised carboxy-group of the hydrolysis of aryl hydrogen malonates
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 23,p. 1538-1540
- https://doi.org/10.1039/c29710001538
Abstract
The hydrolysis of aryl hydrogen malonates is subject to intramolecular general base catalysis by the ionised carboxyl group; general base catalysis of the hydrolysis of the p-nitrophenyl ester shows unexpectedly complex kinetics, and appears to involve a ketene mechanism.Keywords
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