Attainment of an eighteen-electron configuration by means of hydrogen bridging in a purported sixteen-electron pyrazolylborate complex of molybdenum; the structure of (3,5-dimethylpyrazolylborato)dicarbonyl-trihapto-(cycloheptatrienyl)molybdenum
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 777-778
- https://doi.org/10.1039/c39720000777
Abstract
The structural and dynamic properties of [H2B(3,5-dimethylpyrazolyl)]Mo(CO)2C7H7, studied by X-ray crystallography and spectroscopy, show that the molecule is asymmetric with a trihapto-C7H7 ring, a severely bent boat form of the chelate ring, and a 2-electron, 3-centre B–H–Mo bond.Keywords
This publication has 0 references indexed in Scilit: