PHENELZINE COMPOUNDS: COMPLEXES CONTAINING THE PHENELZINIUM(1+) CATION AND COMPLEXES CONTAINING THE FREE BASE
- 1 April 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 14 (4) , 327-334
- https://doi.org/10.1080/00958978608075851
Abstract
The complexes M(phzH)2(SO4)2 (M[dbnd]Mn, Fe, Co, Ni, Zn, phzH [dbnd] monoprotonated β-phenylethyl-hydrazine) have been isolated Evidence from ultraviolet and infrared spectroscopy indicates that they contain six-coordinated metals bonded to phenylethylhydrazinium cations and linked to each other by double sulphato-bridges. Coordination compounds containing β-phenylethylhydrazine have been prepared of three types, MX2(phz)2(M[dbnd]Mn, X[dbnd]Br, M[dbnd]Co, X[dbnd]Cl, Br, I; M[dbnd]Ni, X[dbnd]Br, M[dbnd]Zn, X[dbnd]Br) MX 2(phz) (M[dbnd]Zn, X[dbnd]Cl, Br, NCS) and MX2(phz)3(M[dbnd]Ni, X[dbnd]I). Spectroscopic and magnetic methods have been used to assign structures to these compounds.Keywords
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