Synthesis of halogenated monodispersed telechelic oligomers. III. Bistelomerization of allyl acetate with telogens which exhibit α, ω‐di(trichloromethyled) end groups

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Abstract
The redox bistelomerization of allyl acetate with telogens which exhibit α, ω‐di(trichloromethyled) end groups catalyzed by copper, iron salts, or a ruthenium complex led to monoadducts and telechelic oligomers. These diacetates were quantitatively changed into diols. Such compounds have been characterized by both 1H‐ and 13C‐NMR. A reactivity series has been determined and shows that both end groups must be activated to obtain the expected telechelic products in satisfactory yields.