Structural characterisation of two crystalline modifications of [Au9{P(C6H4OMe-p)3}8](NO3)3: the first example of skeletal isomerism in metal cluster chemistry
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 290-291
- https://doi.org/10.1039/c39840000290
Abstract
[Au9{P(C6H4OMe-p)3}8](NO3)3crystallizes from CH2Cl2–toluene in two crystalline modifications one tetragonal and the other orthorhombic; single crystal X-ray crystallographic determinations on the two modifications have demonstrated that the tetragonal modification has a skeletal geometry derived from an icosahedron and the orthorhombic modification a centred crown skeletal geometry.Keywords
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