Efficient Conversion of Thiols to S-Nitrosothiols with the 18-Crown-6 Complex of N2O4 as a New Nitrosating Agent
- 1 January 1999
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Chemical Research
- No. 11,p. 668-669
- https://doi.org/10.1039/a904784k
Abstract
Gaseous N2O4 reacts with 18-crown-6 to afford a stable ionic complex of NO+·18-crown-6·H(NO3)2 –; this complex is an efficient nitrosating agent for the conversion of thiols to their corresponding S-nitrosothiols in different organic solvents.Keywords
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