Degeneracies Among Terms of a Configuration of Equivalent Electrons
- 1 March 1942
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 61 (5-6) , 305-308
- https://doi.org/10.1103/physrev.61.305
Abstract
If the radial integrals occurring in the term formulae for a configuration assume certain integer ratios given in Table III all elements of the energy matrix become low multiples of a common value. As a consequence high degeneracies are seen to occur. The reason for this behavior is proved to be the existence of an identity [Eq. (6)] concerning sums of products of three integrals of spherical harmonics. The regularity mentioned may serve in the approximate allocation of energy levels or as a check for exact energy formulae. Ostrofsky's formulae for were found to be incorrect in this way. The correct formulae are given in §2.
Keywords
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