t-Butyl Hypochlorite: A Powerful Electrophilic Aromatic Ring Chlorinating Agent
- 1 May 1998
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 28 (10) , 1891-1896
- https://doi.org/10.1080/00397919808007021
Abstract
T-Butyl hypochlorite is an excellent aromatic ring chlorinating agent, under mild conditions, without any catalyst, of acetanilide. High regioselectivity is observed, the product being, nearly exclusively, para-chloroacetanilide.Keywords
This publication has 7 references indexed in Scilit:
- Oxidative Chlorination of Acetanilides with Hydrogen Chloride/m-Chloroperbenzoic Acid/N,N-Dimethylformamide SystemSynthetic Communications, 1991
- Halogenation Using Quaternary Ammonium Polyhalides. XXIV. Chlorination of Acetanilides with Benzyltrimethyl ammonium TetrachloroiodateBulletin of the Chemical Society of Japan, 1990
- Chloration de l'acétanilide et de la benzanilide en présence des cyclodextrines et de l'amyloseCanadian Journal of Chemistry, 1987
- Comparisons of the reactions of chlorine and alkyl hypochlorites with aromatics in nitromethaneThe Journal of Organic Chemistry, 1973
- Aromatic Halogenation with Titanium (IV) Chloride in Presence of Peroxytrifluoroacetic AcidCanadian Journal of Chemistry, 1972
- t-BUTYL HYPOCHLORITEOrganic Syntheses, 1969
- Photochemcial Rearrangement of N-Chloroimides to 4-Chloroimides. A New Synthesis of γ-LactonesJournal of the American Chemical Society, 1964