NEW FOLATE ANALOGS OF THE 10-DEAZA-AMINOPTERIN SERIES - FURTHER EVIDENCE FOR MARKEDLY INCREASED ANTITUMOR EFFICACY COMPARED WITH METHOTREXATE IN ASCITIC AND SOLID MURINE TUMOR-MODELS
- 1 January 1984
- journal article
- research article
- Vol. 12 (1) , 26-30
Abstract
A group of folate analogs of the 10-deaza-aminopterin series, which were designed on the basis of the results of an intensive biochemical and pharmacokinetic program, were examined in therapy experiments utilizing a group of murine tumor models. These new analogs were found to be markedly superior to methotrexate against 4 of 5 ascites tumors (L1210 leukemia, sarcoma 180, Ehrlich carcinoma and Tapper carcinosarcoma) and against 4 of 5 solid tumors (S180, Tapper carcinosarcoma, E0771 mammary adenocarcinoma, Lewis lung carcinoma, and T241 sarcoma). Analogs alkylated (methyl or ethyl) at the 10 position of 10-deaza-aminopterin were the most effective of the group. These analogs achieved log10 reduction in tumor burden several-fold greater magnitude than methotrexate against L1210 and S180 ascites tumors and there were also long-term survivors. 10-Deaza-aminopterin itself gave a result intermediate between those obtained with the 10-alkyl derivatives and methotrexate. Against the solid forms of the Tapper tumor some partial regressions were obtained with methotrexate and 10-deaza-aminopterin, but a far greater number, extending over a longer period were obtained with the 10-ethyl derivative of 10-deaza-aminopterin. Against the E0771 tumor, 10-deaza-aminopterin was 2-fold and the ethyl derivative of 10-deaza-aminopeterin was < 5-fold more effective than methotrexate in retarding tumor growth. Evidence for partial regressions and marked effects against metastic disease were also obtained in the case of the 10-alkyl derivative. Similar results were also obtained with the T241 sarcoma. For Lewis lung carcinoma the relative potency was about the same but overall antitumor effects were more modest.This publication has 12 references indexed in Scilit:
- New folate analogs of the 10-deaza-aminopterin series Basis for structural design and biochemical and pharmacologic propertiesCancer Chemotherapy and Pharmacology, 1984
- Synthesis and antitumor activity of 10-alkyl-10-deazaminopterins. A convenient synthesis of 10-deazaminopterinJournal of Medicinal Chemistry, 1982
- BIOCHEMICAL CORRELATES OF RESPONSIVENESS AND COLLATERAL SENSITIVITY OF SOME METHOTREXATE-RESISTANT MURINE TUMORS TO THE LIPOPHILIC ANTI-FOLATE, METOPRINE1982
- BIOCHEMICAL AND PHARMACOLOGIC PROPERTIES OF A NEW FOLATE ANALOG, 10-DEAZA-AMINOPTERIN, IN MICE1982
- ANTI-TUMOR PROPERTIES OF A NEW FOLATE ANALOG, 10-DEAZA-AMINOPTERIN, IN MICE1978
- THERAPEUTIC RELEVANCE OF DIFFERENCES IN STRUCTURAL SPECIFICITY OF TRANSPORT-SYSTEMS FOR FOLATE ANALOGS IN L1210 TUMOR-CELLS AND IN ISOLATED MURINE INTESTINAL EPITHELIAL-CELLS1977
- Further evidence for a basis of selective activity and relative responsiveness during antifolate therapy of murine tumors.1975
- Differential cell permeability and the basis for selective activity of methotrexate during therapy of the L1210 leukemia.1973
- The cytotoxicity of methotrexate in mouse small intestine in relation to inhibition of folic acid reductase and of DNA synthesis.1971
- Modes of uptake of methotrexate by normal and leukemic human leukocytes in vitro and their relation to drug response.1968