Electrochemical Synthesis of Poly(p-phenylene vinylene) Films

Abstract
Electroreduction of α,α,α′,α′-tetrabromo-p-xylene at an indium tin oxide (ITO), platinum, copper or nickel electrode in ethereal solution afforded a thick and uniform poly(p-phenylene vinylene) film in the undoped state. Addition of Cr(CO)6 or Mo(CO)6 accelerated the film growth at the ITO electrode.

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