Abstract
The compounds CaAgP and CaAgAs have been prepared and their structures have been determined. They are isotypic and crystallize in a modified Fe2P-structure (space group P6̄2m-D3 3h) with the lattice constants: CaAgP a = 704,5(1) pm, c = 417,4(1) pm, CaAgAs a = 720,4(1) pm, c = 427,0(1) pm.

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