Hydroformylation of Heptene-1 Catalyzed by some Inorganic Polymer-Metal Complexes
- 1 February 1989
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 26 (2-3) , 381-389
- https://doi.org/10.1080/00222338908051981
Abstract
Some inorganic polymers and their complexes with Rh or with Co-Ru were prepared. The catalytic behavior of these complexes for the hydroformylation of heptene-1 was studied. It was found that almost all of the rhodium complexes cannot tolerate higher reaction temperature when higher selectivity is wanted, except for the polyalumazane-Rh complex. But the cobalt and ruthenium bimetallic complex of polyalumazane can catalyze the hydroformylation of heptene-1 at higher temperature without any decrease in catalytic activity and with a selectivity of about 70% for branched aldehyde. Other factors affecting conversion and selectivity were also studied in detail.Keywords
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