On grain boundary strength in sintered A12O3

Abstract
Scanning and transmission electron microscopy and the C-Pt replica technique have been used to investigate grain boundary structures in sintered polycrystalline A12O3 with varying concentrations of MgO dopant. A method is proposed for evaluating the fracture toughness, Kβb c, and the strength of grain boundaries from the percentage of intergranular fracture as observed along the path of a propagating macrocrack. The resulting Kβb c is found to be between 0·1 and 0·4 of the value characterizing the fracture toughness of the A12O3 lattice, the observed grain boundary strengths being 400–1300 MPa. A comparison of various alumina structures of different grain boundary strengths but similar microcrack densities and fracture properties indicates that for microscopic fracture processes the distribution of flaw sites is more important than the grain boundary strength.

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