A classical virial theorem for open systems
- 1 April 1977
- journal article
- Published by IOP Publishing in Journal of Physics A: General Physics
- Vol. 10 (4) , 507-515
- https://doi.org/10.1088/0305-4470/10/4/013
Abstract
A generalized classical virial equation is derived, superior to the equations already existing in three respects: (i) applicability to assemblies of fluctuating numbers of particles; (ii) applicability to assemblies subjected to net external action; (iii) applicability to any arbitrarily selected part of a larger assembly. It is found that the momentum in- and out-flux densities, caused by particles crossing the limiting surfaces, contribute to the virial. The equation is applied to a homogeneous gas, and the ideal gas law is derived. Invariance criteria are studied, and translations and division into subsystems are discussed. Various internal and external contributions to the virial are discussed and compared for the new and the already existing virial equations.Keywords
This publication has 8 references indexed in Scilit:
- Sufficient conditions for fragment and regional virial theoremsThe Journal of Chemical Physics, 1974
- Virial Theorem GeneralizedAmerican Journal of Physics, 1974
- Pressure Calculations and the Virial Theorem for Modified Hartree-Fock Solids and AtomsPhysical Review B, 1969
- Scaling problem, virial theorem, and connected relations in quantum mechanicsJournal of Molecular Spectroscopy, 1959
- Kinetic and Potential Energies of an Electron GasPhysical Review B, 1958
- The Virial and Molecular StructureThe Journal of Chemical Physics, 1933
- Bemerkung zum VirialsatzThe European Physical Journal A, 1930
- Ueber einen auf die Wärme anwendbaren mechanischen SatzAnnalen der Physik, 1870