Hydrozirconation of phospha-alkenes and phosphaimines. Evidence for the formation of P–C–Zr and P–N–Zr three-membered rings
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 507-508
- https://doi.org/10.1039/c39900000507
Abstract
Addition of bis(η-cyclopentadienyi)zirconium hydride (Cp2ZrHCl) to phospha-alkenes and phosphaimines leads either to a functionalized bis(η-cyclopentadienyl)zirconium phosphirane and azaphosphirane or to a protonated dico-ordinated phosphorus species.Keywords
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