Hydrogen Bonding in Radical Reactions. Some Remarks on CF3 Radicals
- 1 August 1957
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 27 (2) , 421-422
- https://doi.org/10.1063/1.1743739
Abstract
Studies of the decomposition of acetyl or propionyl peroxide on the one hand and benzoyl peroxide on the other seem to demonstrate that Ph·COO radicals form hydrogen bonds with carboxylic acids, while the nonpolar alkyl radicals do not form such bonds. The formation of hydrogen bonds facilitates the hydrogen transfer between the carboxylic acid and the polar radicals.Keywords
This publication has 5 references indexed in Scilit:
- Heats of Combustion of Some Peroxides and the Heats of Formation of Acetate, Propionate, and Butyrate RadicalsThe Journal of Chemical Physics, 1957
- The Kinetics of Decomposition of Acetyl Peroxide. III. The Reactions of Radicals Produced in the DecompositionJournal of the American Chemical Society, 1954
- Mechanism of the decomposition of acetyl peroxide in acetic-2-C14 acidTransactions of the Faraday Society, 1953
- REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. VI. DECOMPOSITION OF DIACETYL AND OTHER PEROXIDES IN ALIPHATIC ACIDS AND SUBSTITUTED ALIPHATIC ESTERSThe Journal of Organic Chemistry, 1945
- Reactions of Atoms and Free Radicals in Solution. IV. Decomposition of Acetyl Peroxide in Aliphatic Acids—A New Synthesis of Succinic Acid and its Substitution DerivativesJournal of the American Chemical Society, 1943