SYNTHESIS OF CYCLOPENTABBCANOM
- 5 November 1978
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 7 (11) , 1283-1284
- https://doi.org/10.1246/cl.1978.1283
Abstract
Ring contraction by the Favorskii-type rearrangement of α-sulfonyloxycyclohexadecanone (3) gave the corresponding cyclopentadecanecarboxylic acid (5) in a good yield. The acid (5) was converted to cyclopentadecanone (7) via α-phenylthio- (or α-methylthio-)cyclopentadecanecarboxylic acid (6).This publication has 3 references indexed in Scilit:
- Electrosynthesis of Hetero-Hetero Atom Bonds. I. A Direct Preparation of Bis(dialkylthiocarbamoyl) Disulfides from Dialkylamines and Carbon DisulfideBulletin of the Chemical Society of Japan, 1978
- New synthetic reactions. Oxidative decarboxylation of .alpha.-methylthiocarboxylic acids, new approach to acyl anion and ketene synthonsJournal of the American Chemical Society, 1977
- Synthesis of racemic muscone and cyclopentadecanone (exaltone) from 1,9-cyclohexadecadieneThe Journal of Organic Chemistry, 1971