Excess volumes for H2O + D2O liquid mixtures

Abstract
The volume changes on mixing D2O with H2O have been measured with a new tilting-type dilatometer. The molar volumes are very nearly additive, but not exactly so. At 25�C, the excess molar volume Vm is positive, having a maximum value of about 1.8 x cm3 mol-1, while at4�C it is negative, with a minimum of about - 1.2-4 cm3 mol-l.

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