The Syntheses and Properties of the Benzothiazole or Benzimidazole Derivative Adducts of Tin(II, IV) and Antimony(III) Halides

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Abstract
The benzothiazole, 2-amino-benzothiazole, benzimidazole-2-thiol, and benzothiazole-2-thiol adducts of tin(II, IV) chlorides, antimony(III) chloride, and antimony (III) bromide with the formulae of Mn+LmXn− (where L is the ligand and where X is Cl or Br) were synthesized. From their electronic and infrared spectra, it can be seen that the 2-amino-benzothiazole adducts are more stable than those of other ligands and that the metal-ligand bonds in the former remain, even in the ethanolic solution.

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