Synthesis and structure (X-ray diffraction and spectroscopy) of an extremely rigid and non-fluxional trinuclear trihydride, [Rh3H3(η5-C5Me5)3O]PF6·H2O
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 631-633
- https://doi.org/10.1039/c39800000631
Abstract
The trinuclear trihydride [Rh3H3(η5-C5Me5)3O]·PF6·H2O has been synthesised and characterised by X-ray diffraction and spectroscopy; the 1H n.m.r. spectrum shows the molecule to be extremely rigid with a minimumΔG‡ for fluxionality of 109 kJ mol–1.Keywords
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