Photochemistry of Glycosyl Azides
- 1 January 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (1) , 183-185
- https://doi.org/10.1139/v74-028
Abstract
Irradiation with u.v. light of a methanolic solution of β-D-glucopyranosyl (1), α-D-mannopyranosyl (3), or β-D-galactopyranosyl (4) azide affords in good yield the corresponding next-lower aldose. In the case of β-maltosyl (6), β-D-ribofuranosyl (7), or α-L-arabinopyranosyl (8) azide, there was observed the formation of an intermediate which, on standing in the dark, reverts back to starting material.Keywords
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