Coarse-grained microscopic model of glass formers
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- 4 August 2003
- journal article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 100 (17) , 9710-9714
- https://doi.org/10.1073/pnas.1233719100
Abstract
We introduce a coarse-grained model for atomic glass formers. Its elements are physically motivated local microscopic dynamical rules parameterized by observables. Results of the model are established and used to interpret the measured behaviors of supercooled fluids approaching glass transitions. The model predicts the presence of a crossover from hierarchical super-Arrhenius dynamics at short length scales to diffusive Arrhenius dynamics at large length scales. This prediction distinguishes our model from other theories of glass formers and can be tested by experiment.Keywords
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This publication has 27 references indexed in Scilit:
- Glassy Time-Scale Divergence and Anomalous Coarsening in a Kinetically Constrained Spin ChainPhysical Review Letters, 1999
- Calorimetric Study of 3-Bromopentane: Correlation between Structural Relaxation Time and Configurational EntropyThe Journal of Physical Chemistry, 1995
- Formation of Glasses from Liquids and BiopolymersScience, 1995
- Viscous flow in supercooled liquids analyzed in terms of transport theory for random media with energetic disorderPhysical Review Letters, 1987
- Approach to glassy behavior of dielectric relaxation in 3-bromopentane from 298 to 107 KThe Journal of Chemical Physics, 1986
- Kinetic Ising Model of the Glass TransitionPhysical Review Letters, 1984
- Models of Hierarchically Constrained Dynamics for Glassy RelaxationPhysical Review Letters, 1984
- Relaxation in liquids: a defect-diffusion model of viscoelasticityProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1972
- Heat Capacity and Thermodynamic Properties of o-Terphenyl Crystal, Glass, and LiquidThe Journal of Chemical Physics, 1972
- Dielectric Relaxation of Isoamyl BromideThe Journal of Chemical Physics, 1960