A new synthetic route to λ3-iminophosphines involving nucleophilic displacement reactions on aminoiminophosphines
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 187-189
- https://doi.org/10.1039/c39830000187
Abstract
Aminoiminophosphines undergo transamination when treated with highly hindered lithium amides; this observation is exploited in the synthesis of But 3C6H2PNSiMe3, the first thermally stable dico-ordinated phosphrous compound based on the skeleton C–PN.Keywords
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